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X-ray magnetic circular dichroism

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XMCD spectrum of iron

X-ray magnetic circular dichroism (XMCD) is a difference spectrum of two X-ray absorption spectra (XAS) taken in a magnetic field, one taken with left circularly polarized light, and one with right circularly polarized light.[1] By closely analyzing the difference in the XMCD spectrum, information can be obtained on the magnetic properties of the atom, such as its spin and orbital magnetic moment. Using XMCD magnetic moments below 10−5 μB can be observed.[2]

This simple diagram illustrates the general idea of X-ray magnetic circular dichroism. It shows the electronic transitions for 2p→3d (L-edge) absorption. It is not to scale.

In the case of transition metals such as iron, cobalt, and nickel, the absorption spectra for XMCD are usually measured at the L-edge. This corresponds to the process in the iron case: with iron, a 2p electron is excited to a 3d state by an X-ray of about 700 eV.[3] Because the 3d electron states are the origin of the magnetic properties of the elements, the spectra contain information on the magnetic properties. In rare-earth elements usually, the M4,5-edges are measured, corresponding to electron excitations from a 3d state to mostly 4f states.

Line intensities and selection rules

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The line intensities and selection rules of XMCD can be understood by considering the transition matrix elements of an atomic state excited by circularly polarised light.[4][5] Here is the principal, the angular momentum and the magnetic quantum numbers. The polarisation vector of left and right circular polarised light can be rewritten in terms of spherical harmonicsleading to an expression for the transition matrix element which can be simplified using the 3-j symbol:The radial part is referred to as the line strength while the angular one contains symmetries from which selection rules can be deduced. Rewriting the product of three spherical harmonics with the 3-j symbol finally leads to:[4]The 3-j symbols are not zero only if satisfy the following conditions giving us the following selection rules for dipole transitions with circular polarised light:[4]

Derivation of sum rules for 3d and 4f systems

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We will derive the XMCD sum rules from their original sources, as presented in works by Carra, Thole, Koenig, Sette, Altarelli, van der Laan, and Wang.[6][7][8] The following equations can be used to derive the actual magnetic moments associated with the states:

We employ the following approximation:

where represents linear polarization, right circular polarization, and left circular polarization. This distinction is crucial, as experiments at beamlines typically utilize either left and right circular polarization or switch the field direction while maintaining the same circular polarization, or a combination of both.

The sum rules, as presented in the aforementioned references, are:

Here, denotes the magnetic dipole tensor, c and l represent the initial and final orbital respectively (s,p,d,f,... = 0,1,2,3,...). The edges integrated within the measured signal are described by , and n signifies the number of electrons in the final shell.

The magnetic orbital moment , using the same sign conventions, can be expressed as:

For moment calculations, we use c=1 and l=2 for L2,3-edges, and c=2 and l=3 for M4,5-edges. Applying the earlier approximation, we can express the L2,3-edges as:

For 3d transitions, is calculated as:

For 4f rare earth metals (M4,5-edges), using c=2 and l=3:

The calculation of for 4f transitions is as follows:

When is neglected, the term is commonly referred to as the effective spin . By disregarding and calculating the effective spin moment , it becomes apparent that both the non-magnetic XAS component and the number of electrons in the shell n appear in both equations. This allows for the calculation of the orbital to effective spin moment ratio using only the XMCD spectra.

See also

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References

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  1. ^ Zhao, Jijun; Huang, Xiaoming; Jin, Peng; Chen, Zhongfang (April 2015). "Magnetic properties of atomic clusters and endohedral metallofullerenes". Coordination Chemistry Reviews. 289–290: 315–340. doi:10.1016/j.ccr.2014.12.013. ISSN 0010-8545.
  2. ^ Helmut Kronmüller; Stuart S. P. Parkin, eds. (2007). Handbook of magnetism and advanced magnetic materials. Hoboken, NJ: John Wiley & Sons. ISBN 978-0-470-02217-7. OCLC 124165851.
  3. ^ Stöhr, J. (1995-12-15). "X-ray magnetic circular dichroism spectroscopy of transition metal thin films". Journal of Electron Spectroscopy and Related Phenomena. Future Perspectives for Electron Spectroscopy with Synchrotron Radiation. 75: 253–272. doi:10.1016/0368-2048(95)02537-5. ISSN 0368-2048.
  4. ^ a b c de Groot, F.; Vogel, J. (2006). "Fundamentals of X-ray Absorption and Dichroism: The Multiplet Approach". Neutron and X-ray Spectroscopy. pp. 3–66. doi:10.1007/1-4020-3337-0_1. ISBN 978-1-4020-3337-7.
  5. ^ J. Stöhr; Y. Wu (1994). "X-ray Magnetic Circular Dichroism: Basic concepts and theory for 3d transition metal atoms". New Directions in Research with Third-Generation Soft X-Ray Synchrotron Radiation Sources. pp. 221–250. doi:10.1007/978-94-011-0868-3. ISBN 978-94-010-4375-5.
  6. ^ Thole, B. T.; Carra, P.; Sette, F.; van der Laan, G. (1992). "X-ray circular dichroism as a probe of orbital magnetization". Physical Review Letters. 68 (12): 1943–1946. doi:10.1103/PhysRevLett.68.1943.
  7. ^ Carra, P.; König, H.; Thole, B. T.; Altarelli, M. (1993). "Magnetic X-ray dichroism: General features of dipolar and quadrupolar spectra". Physica B: Condensed Matter. 192 (1–2): 182–190. doi:10.1016/0921-4526(93)90119-Q.
  8. ^ Carra, P.; Thole, B. T.; Altarelli, M.; Wang, X. (1993). "X-ray circular dichroism and local magnetic fields". Physical Review Letters. 70 (5): 694–697. doi:10.1103/PhysRevLett.70.694.